. Benzonitrile is a useful solvent and a versatile precursor to many derivatives.  It is a precursor to Diphenylketimine Ph2C=NH (b.p. Phenyl cyanide;Benzonitrile,physical properties,suppliers,CAS,MSDS,structure,Molecular Formula, Molecular Weight ,Solubility,boiling point, melting point Home Products Search Properties Search 中文版: Home > Dictionary > Information: Phenyl cyanide;Benzonitrile Molecular formula : C 7 H 5 N MW : 103.12 CAS, DSC-47-0 nature : density 1.01. He found the compound as a product from the thermal dehydration of ammonium benzoate. A very potent uncoupler of oxidative phosphorylation in mitochondria. He deduced its structure from the already known analogue reaction of ammonium formate yielding formonitrile. Try to do it in a fume hood as isocyanide vapours are toxic, and smells horrible, believe me. , Benzonitrile forms coordination complexes with transition metals that are both soluble in organic solvents and conveniently labile. CN– hydrogen bonding interaction is observed by the HMBC NMR technique for the first time, which provides an efficient approach to directly probe the binding site of the receptor toward CN–. (E)-N-(3,5-Bis(trifluoromethyl)phenyl)-2-(4-(tert-butyl)phenyl)-2-oxoacetohydrazonoyl cyanide (14). Some description was translated by software and the data is only as a reference. Systematic names; Synonyms; Trade names; Database identifiers; Search by chemical structure. CopyCopied, Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agency’s EPISuite, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the, https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:75458, ACD/Labs Percepta Platform - PhysChem Module, US Environmental Protection Agency’s EPISuite, Compounds with the same molecular formula, Search Google for structures with same skeleton, Organic Compound; Aromatic Hydrocarbon; Cyanide Compound; Nitrile; Hydrazine; Organofluoride; Ether; Pollutant; Industrial/Workplace Toxin; Synthetic Compound. In the laboratory it can be prepared by the dehydration of benzamide or by the Rosenmund–von Braun reaction using cuprous cyanide or NaCN/DMSO and bromobenzene. Benzonitrile is a useful solvent and a versatile precursor to many derivatives. FCCP disrupts ATP synthesis by transporting protons across the mitochondrial inner membrane, interfering with the proton gradient.
A hydrazone that is hydrazonomalononitrile in which one of the hydrazine hydrogens is substituted by a p-trifluoromethoxyphenyl group. It reacts with amines to afford N-substituted benzamides after hydrolysis. Applications Laboratory uses. It is mainly used as a precursor to the resin benzoguanamine. Identifiers CAS Number. One example is PdCl2(PhCN)2. (m3/ug)): Mackay model : 0.000393 Octanol/air (Koa) model: 0.0106 Fraction sorbed to airborne particulates (phi): Junge-Pankow model : 0.014 Mackay model : 0.0305 Octanol/air (Koa) model: 0.46 Atmospheric Oxidation (25 deg C) [AopWin v1.92]: Hydroxyl Radicals Reaction: OVERALL OH Rate Constant = 36.8995 E-12 cm3/molecule-sec Half-Life = 0.290 Days (12-hr day; 1.5E6 OH/cm3) Half-Life … CopyCopied, CSID:3213, http://www.chemspider.com/Chemical-Structure.3213.html (accessed 16:52, Nov 13, 2020)
The benzonitrile ligands are readily displaced by stronger ligands, making benzonitrile complexes useful synthetic intermediates.
It is prepared by ammoxidation of toluene, that is its reaction with ammonia and oxygen (or air) at 400 to 450 °C (752 to 842 °F).. Search by chemical names.
The uncoupling agent CCCP is also available.
FCCP also induces apoptosis.Yellow solid, 67%. , In 2018, benzonitrile was reported to be detected in the interstellar medium. He also coined the name benzonitrile which gave the name to all the group of nitriles. 151 °C, 8 mm Hg) via reaction with phenylmagnesium bromide followed by methanolysis. The 2D chemical structure image of 4-[2-(Mesyloxy)ethyl]phenyl isocyanide is also called skeletal formula, which is the standard notation for organic molecules.
FCCP is a potent uncoupler of mitochondrial oxidative phosphorylation. 100-47-0 ... the laboratory it can be prepared by the dehydration of benzamide or by the Rosenmund–von Braun reaction using cuprous cyanide or NaCN/DMSO and bromobenzene. , Except where otherwise noted, data are given for materials in their, "Ueber die Zersetzung des benzoësauren Ammoniaks durch die Wärme", https://en.wikipedia.org/w/index.php?title=Benzonitrile&oldid=986423462, Creative Commons Attribution-ShareAlike License, 188 to 191 °C (370 to 376 °F; 461 to 464 K), This page was last edited on 31 October 2020, at 19:30. 140-29-4 - SUSQOBVLVYHIEX-UHFFFAOYSA-N - Benzyl cyanide - Similar structures search, synonyms, formulas, resource links, and other chemical information. During this step, hydrogens were added, crystal waters were removed, and partial charges were assigned using the OPLS-2005 force …
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